When sodium hypochlorite (bleach) solution is added to luminol, a chemical reaction occurs that releases energy in the form of light. This is called chemiluminescence. The bleach solution acts as an oxidizing agent, which means it takes electrons away from the luminol molecule. This causes the luminol molecule to become excited, and it releases the energy as light.
馃帴 Courtesy: Kendra Frederick
The luminol molecule is made up of two amino groups, a carbonyl group, and an azo group. The amino groups are electron-rich, while the carbonyl group is electron-poor. The azo group is a conjugated system, which means that the electrons in the double bonds can move freely from one atom to another.
When sodium hypochlorite (bleach) solution is added to luminol, the bleach molecules react with the amino groups of the luminol molecule. This reaction takes electrons away from the luminol molecule, which causes the luminol molecule to become oxidized. The oxidized luminol molecule is in an excited state, which means that it has more energy than it normally does.
The excited luminol molecule then releases the extra energy as light. This light is called chemiluminescence. The light emitted by the chemiluminescence reaction is blue because the luminol molecule has a blue fluorescence.
The chemiluminescence reaction between luminol and sodium hypochlorite is catalyzed by the presence of a metal ion, such as iron or copper. The metal ion helps to stabilize the excited state of the luminol molecule, which makes it more likely to release the extra energy as light.
The chemiluminescence reaction is very sensitive to impurities, so it is important to use pure chemicals. The reaction can also be affected by the pH of the solution. The optimal pH for the reaction is around 9.
The chemiluminescence reaction between luminol and sodium hypochlorite can be used to detect blood, as the iron in hemoglobin can catalyze the reaction. The reaction is also used in some commercial products, such as glow sticks and emergency lights.
Scientists develop new molecular system made from abundant element manganese for photooxidation
Highly reducing or oxidizing photocatalysts are a fundamental challenge in photochemistry. Only a few transition metal complexes with Earth-abundant metal ions have so far advanced to excited state oxidants, including chromium, iron, and cobalt. All these photocatalysts require high energy light for excitation and their oxidizing power has not yet been fully exploited. Furthermore, precious and hence expensive metals are the decisive ingredients in most cases.
A team of researchers headed by Professor Katja Heinze of Johannes Gutenberg University Mainz (JGU) has now developed a new molecular system based on the element manganese. Manganese, as opposed to precious metals, is the third most abundant metal after iron and titanium and hence widely available and very cheap. The study is published in the journal Nature Chemistry.
This is my first Oxidation project, a medium sized feeder rat that stands at about 4.5in tall.
Overall he took a month to complete with only about 20 hours in total hands on work. I couldn鈥檛 be happier with how adorable he came out to be and I鈥檓 going to be so happy yet so sad when I get him ready for a new home!